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31.
Almuth Läuter Prakash D. Naik Jai P. Mittal Hans-Robert Volpp Jürgen Wolfrum 《Research on Chemical Intermediates》2007,33(6):513-522
The vibrationally-mediated H2O gas-phase photodissociation was studied at a photolysis wavelength of 248 nm. Single rotational states of the |03−〉|2〉 and |04−〉 H2O overtone vibrations were prepared by laser photoexcitation around 720 nm. H atoms formed in the photodissociation of the
H2O (|04−〉
= 313) were detected by Lyman-α laser-induced fluorescence spectroscopy with sub-Doppler resolution to determine their translational energy. The present
result confirms that in the dissociation process the major part (ca. 93%) of the available energy is released as relative translational energy of the nascent H + OH photofragments, in agreement
with earlier complementary measurements (R. L. Vander Wal, J. L. Scott and F. F. Crim, J. Chem. Phys.
94, 1859 (1991)), where the internal excitation of the OH product radical was investigated at different photolysis wavelengths. 相似文献
32.
33.
Reduction of methyl 6-deoxy-2,3-0-isopropylidene-3-C-methyl-α-L-lyxo-hexopyranosid-4-ulose (2) with sodium tetrahydroborate or L-selectride produces exclusively the L-talo-configurated 4-hydroxy compound (3), which is transformed to methyl 6-deoxy-3,4-O-isopropylidene-3-C-methyl-α-L-talopyranoside (4). Methylation of the 2-hydroxy group and hydrolysis yields L-vinelose (6) . 相似文献
34.
Almuth Laeuter Hans-Robert Volpp Jai P. Mittal Rajesh K. Vatsa 《Journal of Chemical Sciences》2007,119(4):277-282
The collision-free, room temperature gas-phase photodissociation dynamics of CH3CFCl2 (HCFC-141b) was studied using Lyman-α laser radiation (121.6 nm) by the laser photolysis/laser-induced fluorescence ‘pump/probe’ technique. Lyman-α radiation was used both to photodissociate the parent molecule and to detect the nascent H atom products via (2p
2P → 1s
2S) laser-induced fluorescence. Absolute H atom quantum yield, ϕH = (0.39 ± 0.09) was determined by calibration method in which CH4 photolysis at 121.6 nm was used as a reference source of well-defined H atom concentrations. The line shapes of the measured
H atom Doppler profiles indicate a Gaussian velocity distribution suggesting the presence of indirect H atom formation pathways
in the Lyman-α photodissociation of CH3CFCl2. The average kinetic energy of H atoms calculated from Doppler profiles was found to be E
T(lab) = (50 ± 3) kJ/mol. The nearly statistical translational energy together with the observed Maxwell-Boltzmann velocity distribution
indicates that for CH3CFCl2 the H atom forming dissociation process comes closer to the statistical limit. 相似文献
35.
H. M. Liebich O. Al-Babbili G. Huesgen J. W?ll 《Fresenius' Journal of Analytical Chemistry》1976,279(2):148
Ohne Zusammenfassung
Recognition of profiles of alcohols and ketones in urine of patients with diabetes mellitus by gas chromatography and mass fragmentography相似文献
36.
37.
S. Baunack S. Kúdela A. John V. Liebich 《Fresenius' Journal of Analytical Chemistry》1996,355(5-6):633-637
Principal component analysis and cluster analysis have been used in AES investigations of fibre-matrix interactions in alumina fibre reinforced MgLi-alloys prepared by high-pressure infiltration. The samples have been fractured in ultra high vacuum to expose surfaces and interfaces without contamination. All main components exhibit Auger valence band transitions which change their shape with the chemical state. Chemometric methods have been utilized to identify characteristic peak shapes and to classify the investigated areas by composition. Fibre fracture surfaces are characterized by Al, magnesia and Li oxide formed by a redox reaction of alumina with Mg and Li penetrating along grain boundaries. For samples with high silica content a thin interfacial oxide layer on matrix grain boundaries and matrix-fibre interfaces has been found. 相似文献
38.
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40.
F Mayer B K Kr?mer K M Ress V Kühlkamp H M Liebich T Risler L Seipel 《Journal of chromatography. A》1991,572(1-2):339-345
A simplified, rapid and inexpensive extraction procedure for the determination of the antiarrhythmic drug disopyramide and its main metabolite mono-N-desalkylated disopyramide in serum by high-performance liquid chromatography has been developed. The analysis uses ultraviolet detection at 254 nm, and a 5 micron reversed-phase column with a mobile phase of water-triethylamine-acetonitrile-PIC-B8 reagent. Serum extraction is performed with dichloromethane and 1 M sodium hydroxide. p-Chlorodisopyramide is used as internal standard. Recovery rates were 94.5% (S.D. 5.7%) for disopyramide, 96.8% (S.D. 2.2%) for mono-N-desalkylated disopyramide and 97.9% (S.D. 2.8%) for the internal standard. 相似文献